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No Way Jose...Ammonia at $100 to $300 per ton...for 7 years.
Glossary of Terms Greenhouse Gas, GHG: Three types of greenhouse gas, from carbon dioxide to methane to nitrous oxide, have combined to form the climate change dilemma currently challenging our planet. The ice caps at both ends of the planet are melting at a rapid rate. The oceans are warming, and the sea level is changing. The loss of primary agricultural production areas is proposed by scientists. The conclusion is that the overheated planet will no longer be able to sustain life as we know it in another 100 years. CO2, Carbon Dioxide: At 72% of the total, CO2 is the primary gas in the total GHG by weight. Too much carbon is now in the air, heating or trapping heat. CO2 comes primarily from fossil fuel for power, industrial process, and transportation. It also comes from the mining and processing of fossil fuel and the burning of biomass. CH4, Methane: The primary gas in natural gas, CH4 results in 20% of the GHG problem. Natural gas has 18 additional gases that are removed in processing plants before entering the pipeline.
N2O, Nitrous Oxide: Highly potent, one molecule of N2O is equivalent to 300 molecules of CO2. The primary source is agricultural production of fertilized crops at 62.5%.
Formation of Nitrous Oxide: Making nitrous oxide involves two steps. NH4 is converted to NO2 nitrite by Nitrosomonas. The Nitrosomonas can also do back-door reprocesses of nitrite NO2 to form nitrous oxide. The bacterium can shift gears and take a different path under low oxygen, wet soils, to form N2O or nitrous oxide. Nitrous oxide requires a very wet soil to saturated soil to formulate N2O nitrous oxide from NO2 nitrite. Heavy rains, over irrigation, over application of N, and poor soil drainage facilitate the problem when the nitrite conversion NO2 has started. Nitrite NO2 in combination with Nitrosomonas in wet soil conditions converts to N2O nitrous oxide and moves to the atmosphere since it is a gaseous material and much lighter than water. Green Play Ammonia™, NH3: Three atoms of hydrogen are sourced from water and one atom of nitrogen is sourced from the atmosphere. The atoms are high pressure and temperature processed into 82.5% nitrogen and 17.5% hydrogen as pure Anhydrous Ammonia. The hydrogen H2 is released from the electrolysis of H2O. The oxygen O2 goes back into the atmosphere and hydrogen H2 is captured. The H2 hydrogen is used in a German Haber Bosch process. The H2 is a syngas of the purest original type. No fossil fuels are used to build Green Play Ammonia, and no sulfur products and additional gases need to be removed. The original manufacture of all industrial and metallurgical Anhydrous Ammonia was done with electrolysis from hydroelectric dams. Yara is the largest ammonia manufacturer in the world and originally started with hydroelectric dams in Norway. The same is true of the Tennessee Valley Authority (TVA), which started in World War 1 with Wilson Dam on the Tennessee River at Muscle Shoals. Approximately 10,500 KW are required to build one short ton of ammonia. Yielder® NFuel Energy: Used as a registered trademark of Exactrix® Global Systems, the NFuel refers to energy sourced from NH3. About 50% of the plants’ Green Play Ammonia production is utilized for the energy market. The energy levels in ammonia are clean and devoid of carbon. NH3 is one of the best materials on earth for reducing GHG and cooling the planet. Green Play Ammonia can now be used in Selective Catalytic Reaction (SCR) in coal-fired power plants to shave out emissions. The diesel engine can be dual fueled with Green Play Ammonia. A hydrogen cracker can be added to run a strong 20% hydrogen mix into the diesel engine. Fueling can be inclusive of Green Play Bio Diesel from soybeans or canola. The dual markets of energy and crop production allow even greater economic results and lower risk. Anhydrous Ammonia: NH3 is the second largest industrial process in the world behind sulfuric acid production. Ammonia production was developed in 1908 through 1910 by chemists Fritz Haber and Carl Bosch at Max Planck Institute in Berlin. Albert Einstein was good friends with Fritz Haber, which provides a moment of serendipity when these two giants began thinking about how to build the critical material. Ammonia was further perfected on an industrial scale by Carl Bosch (BASF) at Ludwigshafen, Germany in the 1920’s and 1930’s. Ludwigshafen lost about two-thirds of its population in World War 2, and it was a major contributor to the Nazi war machine.
Directly Applied Anhydrous Ammonia: NH3 is directly applied to soil in North America as a general means to apply the next crop year nutrients in the spring, summer and fall work period. The material is stable in the soil and allows advance application up to 18 months ahead of crop need. It is further stabilized by dual application of Thio-sul®, KTS® and TraFix Zn, Mn. Anhydrous Ammonia and Aqua Ammonia are the only primary nitrogen products that can be applied in the fall period before winter sets in. NH4 is always crop available. Ammonia properly applied is stable in the soil. The NH3 is Exactrix® dual applied with P, K and Thio-sul® or Ammonium Thio-sulfates, Zinc Sulfates and Zinc Acetates Mn sulfates when fall banding. If Roundup is applied in pre-plant or Chem-fallow treatments, Mn can be sequestered. The nutrient mix should include Mn to overcome the Roundup attraction to manganese and calcium at the soil surface.
Triple Super Ammonization. Ammoniated Phosphate: During this process, three parts Ammonia N are reacted with one-part phosphate. The analysis would be 120-40-0 to as low as 30-10-0. This dual-product process can only occur in the soil. If applied to the surface, the product would be lost to the atmosphere. The process equipment requires two meters, a 2KC Mass Flow, NH3 high-pressure injector and a 2KM liquid pressure injector. The two injection points do not freeze or bond to the injection equipment. Ammonia 82-0-0 is injected into the flow of the polyphosphate. Ammonium polyphosphate is 10-34-0, while ammonium phosphate is 11-48-0 to 11-55-0 and both are typically safe in the seed row. Diammonium phosphate, DAP, is 18-46-0 and has twice as much free ammonia as single ammoniated phosphate. Diammonium phosphate is a broadcast material and must be used very carefully in the seed row. It not used in high pH 7.5 and greater soils. Ammonium Polyphosphate. 10-34-0 and 11-37-0: 10-34-0 at 1.4 lbs. N and 3.89 lbs. P per gallon weighing 11.7 lbs per gallon as 10-34-0, 11-37-0 is also common in the western U.S. and is 12 lbs. per gallon.
Phosphate Chemistry: Phosphate is 100 times more reactive than ammonia nitrogen. Phosphoric acid is used to etch and clean steel in metal processing, while 82% agricultural grade ammonia stores well in steel tanks and is very compatible with the inside of steel tanks for 50 years. Phosphate reacts with all metals rapidly, including calcium in the soil. The world’s most successful herbicide, Roundup, is built from phosphate. The EPA considers glyphosate to have low toxicity when used at the recommended doses. Roundup or glyphosate application to weeds does not work well if the leaves are dusty, especially in the tire tracks of sprayers. Lake Erie pollution and the floral bloom are most related to the surface application of dry phosphate 11-52-0 in winter months at very high rates. A runoff occurs in the winter, spring and summer, creating a bloom. Crop availability is a critical decision to justify applying phosphate, which is very expensive and a depleting resource. TAPPS, TAPPS+Zn,Mn, Triple Super Ammonization: Tri-Ammonium Polyphosphate with a blend of Ammonium Thio-Sulfate is TAPPS when applied at 1% CV in liquid streaming flows utilizing NH3 82-0-0, Ammonium Polyphosphate 10-34-0, and Ammonium Thio-Sulfate 12-0-0-26S. Included are ammoniated or chelated micronutrients Zn and Mn. TAPPKTS, TAPPKTS+Zn,Mn, Triple Super Ammonization: Tri-Ammonium Polyphosphate with a blend of Potassium Thio-Sulfate is TAPPKTS when applied at 1% CV in liquid streaming flows of NH3 82-0-0, Ammonium Polyphosphate 10-34-0, and Potassium Thio-Sulfate 0-0-17-26S. Included are ammoniated or chelated micronutrients Zn and Mn. Coefficient of Variation at 1%: The 1% CV calculation is used to determine the variation of each NH3 port and each liquid fertilizer APP/ATS port of delivery forming TAPPS and TAPPKTS. Two different products are delivered on a collision in the soil, forming a crystal. An example of 1% CV would be chemicals applied at 100 pounds per acre, where one pound of 100 pounds applied is not crop available. A 95% chance exists that the CV value will repeat again. Some CVs are as high as 33% to 50% in fertilizer application. This means 33% to 50% of the material is not crop useable. This means the risk has become very high and the chance of using the material successfully is poor and may incur a 50% loss. The 50% balance is lost into the environment. Uniformity of application is often mentioned in scientific presentations, but seldom do producers understand how critical uniformity of application is to the success with chemicals. Producers may only think of the per-acre rate as being targeted and found to be excellent for costing. Some producers think they can apply twice and get a uniform application. The CV gets worse the more the producer uses the inaccurate applicator and then adds another variable to the commentary, such as a windy day or a rolling slope. · The coefficient of variation (CV) is a statistical measure of the dispersion of data points in a data series around the mean. · In finance, the coefficient of variation allows investors to determine how much volatility, or risk, is assumed in comparison to the amount of return expected from investments. · The lower the ratio of the standard deviation to mean return, the better risk-return tradeoff. · Knowing there is a 95% chance the event will happen again as calculated allows good decisions to be made. Binary Banding, with P-51 Openers, Root Pattern Geometry: Using the indexing technique of twin bands of placed nutrients, a corn or cotton root system can absorb nutrients immediately after planting.
Liquid Streaming Flows at 1% CV: Streaming flows in lineal bands allow the plant roots to access balanced NPKS and micronutrients such as Zn, Mn.
Thio-Sul® or ATS, Ammonium Thio-Sulfate: At 11.15 pounds per gallon at 12-0-0-26S, 1.1 lbs. N and 2.89 lbs. S per gallon, this is a combination performance material with two sources of sulfur.
KTS® or Potassium Thio-Sulfate, 0-0-25-17S: At 12 pounds per gallon or 3 lbs. K and 2.1 lbs. S per gallon, this material is a reliable solution. Developed and marketed by Tessenderlo Kerley Inc. and now available from 5 other manufacturers, the material performs well in cold weather and provides high crop availability when blended with phosphate to help form TAPPKTS with Zn and Mn.
Urea Ammonium Nitrate, URAN and UAN: The third-tier nitrogen product is used for salvage and convenience in crop production. It involves 25% mobile nitrate, 50% urea and 25% ammonium or three types of nitrogen. These products are very corrosive to steel. They are also dangerous to the environment when over applied. The Gulf of Mexico Hypoxia and Rhine River contamination is directly related to these products being incorrectly applied at too high of a rate. Urea: Known as a second-tier nitrogen product, urea is not primary nitrogen like the Anhydrous Ammonia or Aqua Ammonia that are immediately crop available. The 46-0-0 product combines CO2 into granules to build a carbamide. It is a CO2-based material with two NH2 molecules attached. The CO2 must be released into the environment before NH4 can be formed. As a result, Urea should not receive a carbon credit since it is built from CO2 coming from the fossil fuel ammonia plant.
Micronutrients: Typically used in small amounts from 2 pounds per acre to .05 pounds per acre, these micronutrient metals are vital in the formation of proteins and amino acids, plus they allow favorable bacteria like yeast to flourish in the soil. The micronutrients are naturally occurring metals that can be ammoniated or chelated. They are zinc, manganese, copper, iron, moly, boron and sometimes nickel and selenium. Silver may be a micronutrient and is being investigated.
No-tillage Deep Band: Banding at a depth of 6 to 9 inches in narrow opener slots of .375-inch width reduces the NH4 diffusion zone and concentrates the band of TAPPKTS, which reduces the feeding sites for Nitrosomonas. The band is most stable at this depth since the zone is anaerobic or has very little oxygen to support soil microbes like Nitrosomonas. Ammoniated: Ammonia is introduced into the PKS and micros fertilizer manufacturing process with this technique. It provides a better target for plant roots. A synergism is developed between such products as NH3 and phosphate, plus potassium is much more efficient when it is ammoniated. All starter fertilizers include ammonia for quick nitrogen uptake. Nitrate fertilizers are not used for starter fertilizers. A costly fertilizer built by Ortho did have some nitrate in the analysis 27-12-0-7S. That nitrate in the 27 analysis or 50% of the N value was wasted since plants like corn, wheat and cotton cannot use nitrate in the first 30 days. NPKS+Zn,Mn: The name includes the chemical nutrients found in TAPPKTS plus zinc and manganese. Zinc is a bacteria-stat for Nitrosomonas. Zinc improves yeast formation in the soil. Manganese also feeds certain types of bacteria. Both materials are viable plant nutrients in very small amounts applied. Nitrosomonas: A bacterium known as the “The bandito and the archenemy of nitrogen stability,” Nitrosomonas converts NH4 or ammonium to mobile nitrate and can form N2O nitrous oxide from NO2 nitrite.
NFuel: Versatile NFuel is NH3 used as fuel for engines, SCR, heating and rocket engines. NFuel can also be cracked for the H2 only. NFuel stores well in steel pressure vessels. NFuel is a battery when hydrogen storage is made economically. NFuel transports much more safely than H2, hydrogen. NFuel is the success story primed and ready to drive the hydrogen economy. Cover Cropping: When an economic growing crop is moving to maturity, cover cropping seeding is a means to protect the soil and maintain a green link in the soil life. The soil can stay alive and operate as a powerful organism colony. Cover cropping is used in short rotations, where more rain falls than the crop needs. It is a mix of up to 14 different species that function independently and together in cool weather and warm weather. The technique is a powerful additional tool to drive No-till farming and harvest carbon or CO2 from the atmosphere and store it deep in the soil. Cover cropping helps. Fumigant Cover Cropping: Continuous rotations of corn require an interloping fumigation to maintain good yields. Fumigation with cyanide gas from plant glucosinolates reduces nematodes when crops like fumigant mustard are planted in the early spring. Spring is when nematodes move up to the top three feet of the soil. Another great choice for fumigation is winter rape and winter canola, which have much deeper roots and more soil mass coverage. Thus, winter canola and winter rape provide longer term suppression of nematodes. Syngas: This resource can be produced from many sources, including natural gas, coal, biomass, or virtually any hydrocarbon feedstock, by reaction with steam, carbon dioxide, or oxygen. Syngas is a crucial intermediate resource for the production of hydrogen, ammonia, methanol, and synthetic hydrocarbon fuels. Production methods include steam reforming of natural gas or liquid hydrocarbons to produce hydrogen, the gasification of coal, biomass, and in some types of waste-to-energy gasification facilities. NP or Natural Gas: Natural is a misnomer since natural gas comes from oil field gas and must be processed before becoming CH4 or methane. Oil field gas has 18 different gasses present that must be removed to make syngas methane for the steam reformation of ammonia production. Electrolysis: The original method to make NH3, this process is in broad use. An electrical current is applied to distilled water, and H2 and O2 are split off to create NH3. The H2 immediately goes to the Haber Bosch processor. Haldor Topsoe, https://www.topsoe.com, is the major manufacturer of efficient electrolyzers in big NH3 plants using wind power. Yara is the major builder of NH3 using electrolyzers and wind power. Non-Fossil Fuels, Photo Voltaic or PV, Wind Turbine Power, Water Turbine Power, Biomass, Ethanol, Bio Diesel, Nuclear Sources of Power: These developments are the future of low GHG emissions. Fossil fuels may not be able to compete in cost, performance, and making hydrogen and NH3 fuel availability more local. Locally built energy has a pleasant result when GHG is removed from the process. Fossil fuels will never be replaced, but a big tonnage or volume dent needs to occur immediately. Every sector of the economy is looking for overwhelming progress in solving the GHG problem. Aerobic Depth: Infrared light will not penetrate beyond this soil depth of 4 inches to 5 inches. As a result, the soil surface above 4 to 5 inches contains good oxygen, thus allowing high levels of bacterial and fungal activity. The aerobic zone is loaded with carbon and exchange products that build soils and feed microflora. Anaerobic Depth: Considered the topsoil or plow layer, this soil depth from 4 inches to 10 inches allows very little oxygen to exist that would allow bacteria to proliferate in this zone. Roots introduce exchange products in the root zone. Nitrous oxide has very little chance to form up if No-tillage nutrients are placed deep in the soil in tight narrow bands of TAPPKTS plus zinc and manganese. Cover cropping is also key to developing soils and keeping nitrous oxide to a minimum. Oligarch: Not quite a monopolist like Andrew Carnegie of Carnegie Steel becoming JP Morgan’s U.S. Steel or John Rockefeller’s Standard Oil, the Oligarch companies of North America still maintain a firm, unrelenting grip and international grip on the fertilizer market.
Nitrogen Types: Primary nitrogen is NH3 at 82% N and Aqua Ammonia at 20% to 28% N in the first tier.
Tillage Types: Tillage management is essential, from the plow to the chemical control of weeds.
Bezos $10 Billion Earth Fund
Jeff Bezos in 2016 On February 17, 2020, Jeff Bezos announced over Instagram that he was donating $10 billion to a new organization called the Jeff Bezos Earth Fund to fight climate change. He wrote, “Climate change is the biggest threat to our planet,” adding that, “I want to work alongside others both to amplify known ways and to explore new ways of fighting the devastating impact of climate change on this planet we all share.”[2] He will “begin issuing grants this summer.”[2] Your Great
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